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Looking through the Reference Manual for the STM32H7xx I see there is another Dual mode called Interleaved. It seems likely that by putting an input signal into two Analog Input pins (e.g. A0 and A1) and enabling Dual interleaved mode it will be possible to sample at twice the current maximum rate. So, instead of say 2.9MS/sec we can reach 5.8MS/sec at 16b resolution.
Also, one can also enable a single DMA to handle this dual interleaved data so that all the captured data needs to re-arranging once retrieved from the DMA buffers.
I'm going to try some experiments and see if it works.