diff --git a/spec/API_specification/dataframe_api/dataframe_object.py b/spec/API_specification/dataframe_api/dataframe_object.py
index c133d79a..c0d30431 100644
--- a/spec/API_specification/dataframe_api/dataframe_object.py
+++ b/spec/API_specification/dataframe_api/dataframe_object.py
@@ -452,6 +452,17 @@ def __divmod__(self, other: DataFrame | Scalar) -> tuple[DataFrame, DataFrame]:
         """
         ...
 
+    def __invert__(self) -> DataFrame:
+        """
+        Invert truthiness of (boolean) elements.
+
+        Raises
+        ------
+        ValueError
+            If any of the DataFrame's columns is not boolean.
+        """
+        ...
+
     def __iter__(self) -> NoReturn:
         """
         Iterate over elements.
@@ -467,12 +478,22 @@ def __iter__(self) -> NoReturn:
     def any(self, skipna: bool = True) -> DataFrame:
         """
         Reduction returns a 1-row DataFrame.
+
+        Raises
+        ------
+        ValueError
+            If any of the DataFrame's columns is not boolean.
         """
         ...
 
     def all(self, skipna: bool = True) -> DataFrame:
         """
         Reduction returns a 1-row DataFrame.
+
+        Raises
+        ------
+        ValueError
+            If any of the DataFrame's columns is not boolean.
         """
         ...